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Title :Mn(III)-Based Oxidation of Methoxynaphthalenes with 3-Oxobutanamides
Authors :Cong, Zhiqi
Nishino, Hiroshi
Issue Date :Dec-2006
Citation jtitle :熊本大学極低温装置室ユーザー研究報告書 : 熊大極低温
vol. :17
start page :5
end page :8
Abstract :Oxidation of a mixture of 2,7-dimethoxynaphthalene and N-phenyl-3-oxobutanamide with manganese(III) acetate in acetic acid at reflux temperature gave direct 3-oxobutanamide-substituted naphthalene, naphtho[2,1-b]furan and lactam derivatives in moderate yields, respectively. The same procedure could be applied to a combination of other 2-methoxyl substituted naphthalenes with various 3-oxobutanamides, and the homologues were obtained in similar yields. The characterization of the reaction products, the examination of the optimum reaction conditions, and the mechanism for the formation of the products were discussed.
Type Local :紀要論文
Publisher :熊本大学
Comment :文末に Supporting information あり
URI :http://hdl.handle.net/2298/12277
Appears in Collections:Cryogenics Report of KUMAMOTO University
Please use this identifier to cite or link to this item: http://hdl.handle.net/2298/12277