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Title :Development of a Model for Analyzing the Temperature Dependence of the Viscosity of Ion Conducting Polymers and Ionic Liquids
Authors :Aniya, Masaru
Ikeda, Masahiro
Ndeugueu, Jean Leopold
Issue Date :Sep-2014
Citation jtitle :Arabian Journal for Science and Engineering
vol. :39
no. :9
start page :6627
end page :6633
Abstract :The bond strength-coordination number fluctuation (BSCNF) model of the viscosity developed by the authors considers that the viscous flow occurs by breaking and twisting the connections between the structural units that form the melt. The analytical expression of the viscosity that results from such processes is written in terms of the average bond strength, the average coordination number, and their fluctuations of the structural units. In the present study, we use the BSCNF model to investigate the temperature dependence of the viscosity of ion conducting polymers LiClO_4-PPG and NaCF_3SO_3-PPG, and ionic liquids[bmim][PF_6], [bpy] [BF_4], [bmpro][(CF_3SO_2)_2N], [bpy] [(CF_3SO_2)_2N] and [bmim][(CF_3SO_2)_2N]. For ion conducting polymers, the analysis of the α-relaxation process is also presented. A case study done for ionic liquids indicates that the cooperativity for molecular motion which is evaluated from the viscosity analysis can be correlated with the diffusion coefficients and the ionic conductivities. The results of this study indicate that the BSCNF model is an effective model that could be used to analyze and interpret the measured temperature dependence of the viscosity.
URL :http://link.springer.com/article/10.1007%2Fs13369-014-1187-3
Type Local :雑誌掲載論文
ISSN :13198025
Publisher :Springer Berlin Heidelberg
Comment :【著者所属】安仁屋勝:熊本大学大学院自然科学研究科(理学系)物理科学 / 池田昌弘:福井工業高等専門学校 / Sahara, Jean Leopold Ndeugueu:熊本大学大学院自然科学研究科
URI :http://hdl.handle.net/2298/33503
Appears in Collections:Journal Article (Sciende)
Please use this identifier to cite or link to this item: http://hdl.handle.net/2298/33503